The workshop explores the transformative intersection of large language models (LLMs) and modern database technologies. As LLMs become integral to data-driven applications, new opportunities and challenges emerge in query optimization, natural language interfaces, search, schema refinement and responsible data management. This workshop brings together researchers and practitioners to discuss advances in LLM-augmented database systems, efficient infrastructure for LLM serving, and responsible integration practices. Participants will share their research, and case studies, fostering collaboration at the forefront of generative AI and data management-aligned with CASCON’s vision for trustworthy, high-performance, and sustainable computing