Affective computing encompasses a broad field of research ranging from emotion recognition in development artifacts to interdisciplinary problem solving, and is of interest to software systems as they are designed and used by humans. For requirements engineering (RE), the understanding and use of human and social aspects plays a crucial role in various facets ranging from the consideration of individual professionals and team performance during RE activities to the use of end-user emotions as a means to validate requirements. The AffectRE workshop aims to create an international, sustainable community where researchers and practitioners can meet, present, and discuss their current work to impact the RE community with ideas from the field of Affective Computing. In its fifth edition, this workshop encourages high quality contributions of empirical studies, theoretical models, and tools that raise awareness of emotions in RE.