The Notification Listener Service (NLS) in Android allows third-party apps to monitor and process device notifications, enabling powerful features but also introducing security and privacy risks. Despite the special permission required to access NLS, it has been recurrently exploited by malicious actors. However, there is a lack of systematic investigation into NLS usage patterns and their security implications. In this paper, we propose NLRadar, a hybrid approach combining static analysis and LLM to examine NLS usage in Android apps. We apply NLRadar to a large scale of apps, including both malware and regular apps, to demystify NLS usage and to uncover abuses. Our analysis reveals that NLS is heavily abused, with interesting discoveries such as apps insecurely storing social media messages, exploiting NLS for destructive competition or SMS credential stealing, and leveraging NLS to spread promotional messages or even malicious links. We also find undisclosed changes in NLS usage through app updates and inadequate disclosure in privacy policies. Our findings emphasize the need for more rigorous vetting of NLS usage and better developer education on responsible NLS practices.