Deep learning (DL) plays a more and more important role in our daily life due to its competitive performance in industrial application domains. As the core of DL-enabled systems, deep neural networks (DNNs) need to be carefully evaluated to ensure the quality of the trained model meets the demand. In practice, the \emph{de facto standard} to assess the quality of DNNs in the industry is to check their performance (accuracy) on a collected set of labeled test data. However, preparing such labeled data is often not easy partly because of the huge labeling effort, i.e., data labeling is labor-intensive, especially with the massive new incoming unlabeled data every day. Recent studies show that test selection for DNN is a promising direction that tackles this issue by selecting minimal representative data to label and using these data to assess the model. However, it still requires human effort and cannot be automatic. In this paper, we propose a novel technique, named \textit{Aries}, that can estimate the performance of DNNs on new unlabeled data using only the information obtained from the original test data. The key insight behind our technique is that the model should have similar prediction accuracy on the data which have similar distances to the decision boundary. We performed a large-scale evaluation of our technique on 2 famous datasets, CIFAR-10 and Tiny-ImageNet, 4 widely studied DNN models including ResNet101 and DenseNet121, and 13 types of data transformation methods. Results show that the estimated accuracy by \textit{Aries} is only 0.03% – 2.60% off the true accuracy. Besides, \textit{Aries} also outperforms the state-of-the-art labeling-free methods in 50 out of 52 cases and selection-labeling-based methods in 96 out of 128 cases.